S.P.R. The general aim is to allow for an improved understanding of the material’s temperature-, pressure- and time-dependent properties taking into consideration additional mechanical and atmospheric loads. The crystalline structure has a marked effect on the mechanical properties and particularly the impact strength of the film. Part of Springer Nature. Biomacromolecules 19(12):4542–4553, Behrens AM, Casey BJ, Sikorski MJ, Wu KL, Tutak W, Sandler AD, Kofinas P (2014) In situ deposition of PLGA Nanofibers via solution blow spinning. Chem Eng Sci 203:220–227, Abdal-Hay A, Barakat NM, Lim JK (2012) Novel technique for polymeric Nanofibers preparation: air jet spinning. The main blow spun polymer systems: processing conditions and applications. Any processing condition that causes faster cooling, for example, a lower freeze line distance, will lead to improved impact strength. Journal of Polymer Research The applications can cover both CFD for polymer processing including ANSYS Polyflow as well as ANSYS FEA for polymer processing and can include mixing, extrusion, blow molding, drop and impact analysis. Because the - 212.129.61.156. volume 27, Article number: 205 (2020) J Appl Polym Sci 133(18):43379, RMDC F, Menezes RR, Oliveira JE, de Medeiros ES (2015) Production of submicrometric fibers of mullite by solution blow spinning (SBS). Shrinkage is of order 10-100/1000 for unfilled and 1-10/1000 for filled across the thickness From Boothroyd et al 30 J Appl Polym Sci 133(9):43025, Costa RGF, Brichi GS, Ribeiro C, Mattoso LHC (2016) Nanocomposite fibers of poly(lactic acid)/titanium dioxide prepared by solution blow spinning. Cite this article. Polymer 46(10):3372–3384, Rajendran M, Bhattacharya AK (2004) Production of rare-earth orthoferrite ceramic fibres by aqueous sol-gel blow spinning process. The temp limits are set by the polymer … J Appl Polym Sci 134(19):44802, Bolbasov EN, Stankevich KS, Sudarev EA, Bouznik VM, Kudryavtseva VL, Antonova LV, Matveeva VG, Anissimov YG, Tverdokhlebov SI (2016) The investigation of the production method influence on the structure and properties of the ferroelectric nonwoven materials based on vinylidene fluoride – tetrafluoroethylene copolymer. Eur Polym J 54:1–10, Oliveira JE, Zucolotto V, Mattoso LH, Medeiros ES (2012) Multi-walled carbon nanotubes and poly(lactic acid) nanocomposite fibrous membranes prepared by solution blow spinning. Mater Sci Eng C Mater Biol Appl 48:372–377, CAS  Learn more about Institutional subscriptions, Kuk E, Ha Y-M, Yu J, Im I-T, Kim Y, Jung YC (2016) Robust and flexible polyurethane composite Nanofibers incorporating multi-walled carbon nanotubes produced by solution blow spinning. Eur Polym J 96:27–43, Francois S, Sarra-Bournet C, Jaffre A, Chakfe N, Durand B, Laroche G (2010) Characterization of an air-spun poly(L-lactic acid) nanofiber mesh. Until today, suitable measuring techniques giving insights in the material’s behavior under a variety of different process parameters are rarely accessible while techniques taking into account solely singular influences are still commonly applied. The general aim is to allow for an improved … RSC Adv 6(87):83783–83801, Daristotle JL, Behrens AM, Sandler AD, Kofinas P (2016) A review of the fundamental principles and applications of solution blow spinning. If a material is more resistant to flow and you must make it flow anyway, you have to provide more force and adjust other conditions, like temperature. Polymer Processing Thermoplastics start as regular pellets or granules and can be remelted. PubMed  Polymer 73:42–51, Lopes AR (2016) Caracterização de soluções poliméricas para aplicação em revestimentos para a conservação de produtos alimentares. Introduction Polymer dissolution plays a key role in many industrial applications in a variety of areas, and an understanding of the dissolution process allows for the optimization of design and processing conditions, as well as selection of … Polym Test 60:140–148, Rempel SP, Engler LG, Soares MRF, Catafesta J, Moura S, Bianchi O (2019) Nano/microfibers of EVA copolymer obtained by solution blow spinning: processing, solution properties, and pheromone release application. L.D. ACS Macro Lett 1(8):1032–1036, Bolbasov EN, Anissimov YG, Pustovoytov AV, Khlusov IA, Zaitsev AA, Zaitsev KV, Lapin IN, Tverdokhlebov SI (2014) Ferroelectric polymer scaffolds based on a copolymer of tetrafluoroethylene with vinylidene fluoride: fabrication and properties. et al. Indian J Fibre Text Res 42(1):38–42, Deneff JI, Walton KS (2019) Production of metal-organic framework-bearing polystyrene fibers by solution blow spinning. Master's thesis, Universidade D Coimbra, Regev O, Vandebril S, Zussman E, Clasen C (2010) The role of interfacial viscoelasticity in the stabilization of an electrospun jet. Biosensors (Basel) 2(1):70–82, Ahmed J, Matharu RK, Shams T, Illangakoon UE, Edirisinghe M (2018) A comparison of electric-field-driven and pressure-driven Fiber generation methods for drug delivery. ABS Processing Conditions Acrylonitrile-butadiene Styrene (ABS) has a broad processing window and can be processed on most standard machinery. J Memb Sci J 311(1–2):259–269, Vasireddi R, Kruse J, Vakili M, Kulkarni S, Keller TF, Monteiro DC, Trebbin M (2019) Solution blow spinning of polymer/nanocomposite micro−/nanofibers with tunable diameters and morphologies using a gas dynamic virtual nozzle. In this lesson we are going to do Polymer Processing part 1 where we will be introducing ways to make libraries a polymers that explore processing conditions. Therefore, viscosity is especially important for polymer processing. and O.B. Polym Eng Sci 59(S1):E171–E181, Chen C, Townsend AD, Sell SA, Martin RS (2017) Microchip-based 3D-cell culture using polymer Nanofibers generated by solution blow spinning. Biomed Phys Eng Express 2(3):035007, Molnár K, Mészáros L (2020) Editorial corner – a personal view: the role of electrospun nanofibers in the fight against the COVID-19. J Eur Ceram Soc 24(1):111–117, Hildebrand JH, Scott RL (1964) The solubility of nonelectrolytes3d edn. It involves not only the shaping but also the synthesis, transformation, compounding, functionalization, and stabilization of materials. Ind Eng Chem Res 55(1):323–333, Abdal-hay A, Hamdy AS, Lim JH (2014) Facile preparation of titanium dioxide micro/nanofibers and tubular structures by air jet spinning. Thermosetting materials start as liquids/syrups, often called "resins", as powders or partially cured … Google Scholar, Medeiros ELG, Braz AL, Porto IJ, Menner A, Bismarck A, Boccaccini AR, Lepry WC, Nazhat SN, Medeiros ES, Blaker JJ (2016) Porous bioactive Nanofibers via cryogenic solution blow spinning and their formation into 3D macroporous scaffolds. Mater Sci Eng C Mater Biol Appl 49:681–690, Oliveira JE, Moraes EA, Costa RGF, Afonso AS, Mattoso LHC, Orts WJ, Medeiros ES (2011) Nano and submicrometric fibers of poly(D,L-lactide) obtained by solution blow spinning: Process and solution variables. J Nanosci Nanotechnol 15(1):616–627, Oliveira JE, Moraes EA, Marconcini JM, LHC M, Glenn GM, Medeiros ES (2013) Properties of poly(lactic acid) and poly(ethylene oxide) solvent polymer mixtures and nanofibers made by solution blow spinning. ACS Appl Mater Interfaces 10(49):41924–41934, Santos AMC, Medeiros ELG, Blaker JJ, Medeiros ES (2016) Aqueous solution blow spinning of poly(vinyl alcohol) micro- and nanofibers. J Appl Polym Sci 136(15):47337, Teno J, González-Gaitano G, González-Benito J (2017) Nanofibrous polysulfone/TiO2 nanocomposites: surface properties and their relation with E. coliadhesion. J Biomed Mater Res B Appl Biomater 107(5):1462–1470, Hell AF, Simbara MMO, Rodrigues P, Kakazu DA, Malmonge SM (2018) Production of fibrous polymer scaffolds for tissue engineering using an automated solution blow spinning system. Dent Mater J 37(3):465–473, Cerna Nahuis LE, Alvim Valente C, de Freitas OD, de Souza Basso NR, Antonio Malmonge J (2019) Preparation and characterization of polymeric microfibers of PLGA and PLGA/PPy composite fabricated by solution blow spinning. ACS Biomater Sci Eng 2(9):1442–1449, Tomecka E, Wojasinski M, Jastrzebska E, Chudy M, Ciach T, Brzozka Z (2017) Poly(l-lactic acid) and polyurethane nanofibers fabricated by solution blow spinning as potential substrates for cardiac cell culture. The effect of process conditions and post-processing steps Google Scholar, Hoffman K, Skrtic D, Sun J, Tutak W (2015) Airbrushed composite polymer Zr-ACP nanofiber scaffolds with improved cell penetration for bone tissue regeneration. Polymer processing is commonly defined as the “activity performed on polymeric materials to increase their usefulness”. We performed a systematic study of the effect of processing conditions on the performance of P3HT:PCBM solar cells. moist conditions cause polymer moisture absorption. J Nanosci Nanotechnol 15(8):5628–5636, da Silva Parize DD, Foschini MM, de Oliveira JE, Klamczynski AP, Glenn GM, Marconcini JM, Mattoso LHC (2016) Solution blow spinning: parameters optimization and effects on the properties of nanofibers from poly(lactic acid)/dimethyl carbonate solutions. So the learning outcomes here are to give an overview of Polymer Processing in which we are going to focus on Melt Processing … ACS Macro Lett 3(3):249–254, Srinivasan S, Chhatre SS, Mabry JM, Cohen RE, McKinley GH (2011) Solution spraying of poly(methyl methacrylate) blends to fabricate microtextured, superoleophobic surfaces. J Biomed Mater Res B Appl Biomater 106(6):2435–2446, Suarez-Franco JL, Vazquez-Vazquez FC, Pozos-Guillen A, Montesinos JJ, Alvarez-Fregoso O, Alvarez-Perez MA (2018) Influence of diameter of fiber membrane scaffolds on the biocompatibility of hPDL mesenchymal stromal cells. The material moisture content should … Suggested drying conditions are 80 - 90 C (176 - 195 F) for a minimum of 2 hours. Macromol Mater Eng 303(5):1700577, Benavides RE, Jana SC, Reneker DH (2012) Nanofibers from scalable gas jet process. The drying conditions… Markets Polymer Processing Polymer Synthesis DMSO is a powerful solvent capable of dissolving highly insoluble monomers and retaining high molecular weight polymers in solution, which makes it the ideal solvent for a number of polymer … J Appl Polym Sci 130(2):1383–1391, Sinha-Ray S, Sinha-Ray S, Yarin AL, Pourdeyhimi B (2015) Theoretical and experimental investigation of physical mechanisms responsible for polymer nanofiber formation in solution blowing. POLYMER CRYSTALLIZATION UNDER PROCESSING CONDITIONS TABLE I Physical and Transport Properties Material ρ (kg m−3) Cp (J Kg−1 K−1) K(W m−1 K−1) Tm ( C) Cu–Be 2% alloy 8200 500 100 … and O.B. Mater Sci Eng C Mater Biol Appl 40:32–41, Medeiros ES, Glenn GM, Klamczynski AP, Orts WJ, Mattoso LHC (2009) Solution blow spinning: a new method to produce micro- and nanofibers from polymer solutions. Then reduce temperatures to Ingeo conditions… Polymer processing is commonly defined as the “activity performed on polymeric materials to increase their usefulness”. https://doi.org/10.1177/155892501300800111, Shi L, Zhuang X, Tao X, Cheng B, Kang W (2013) Solution blowing nylon 6 nanofiber mats for air filtration. Biomed Mater 11(3):035001, PubMed  1. https://doi.org/10.1016/j.jece.2018.11.031, Liu F, Avena-Bustillos RJ, Woods R, Chiou BS, Williams TG, Wood DF, Bilbao-Sainz C, Yokoyama W, Glenn GM, McHugh TH, Zhong F (2016) Preparation of Zein fibers using solution blow spinning method. Polymers face many of the same problems as pigments. J Environ Chem Eng 5(3):2515–2523, Ren J, Huang X, Wang N, Lu K, Zhang X, Li W, Liu D (2016) Preparation of polyaniline-coated polyacrylonitrile fiber mats and their application to Cr(VI) removal. Significant shear is required during processing … Dietmar DrummerPhone: +49 (0)9131 / 85-29700E-mail: drummer@lkt.uni-erlangen.deHomepage: Institute of Polymer Technology. The authors declare that they have no conflict of interest regarding the publication of this article. Although other studies had already presented the SBS parameters and their correlations with fiber morphology, it’s still unclear for polymeric researchers which systems have already been tested, therefore some questions remain unanswered, such as: “which polymers have been used most in the art?”, “which solvents have promoted the fiber formation?”, “which additives or particles were tested for composite polymer fibers?”, “for which applications have the fibers been targeted?”, “what adaptations have been investigated to overcome the challenges of the process?”. Polymer 21(3):258–262, Cheng B, Tao X, Shi L, Yan G, Zhuang X (2014) Fabrication of ZrO2 ceramic fiber mats by solution blowing process. It is therefore important to dry the material prior to molding. J Nanosci Nanotechnol 12(3):2733–2741, Oliveira JE, Medeiros ES, Cardozo L, Voll F, Madureira EH, Mattoso LH, Assis OB (2013) Development of poly(lactic acid) nanostructured membranes for the controlled delivery of progesterone to livestock animals. Melt fracture is a type of flow instability that begins as a roughening of the surface … J Food Sci 82(6):1402–1411, Paschoalin RT, Traldi B, Aydin G, Oliveira JE, Rutten S, Mattoso LHC, Zenke M, Sechi A (2017) Solution blow spinning fibres: new immunologically inert substrates for the analysis of cell adhesion and motility. Mater Chem Phys 182:338–346, da Silva Parize DD, de Oliveira JE, Foschini MM, Marconcini JM, Mattoso LHC (2016) Poly(lactic acid) fibers obtained by solution blow spinning: effect of a greener solvent on the fiber diameter. Polymer 56:452–463, Stojanovska E, Canbay E, Pampal ES, Calisir MD, Agma O, Polat Y, Simsek R, Gundogdu NAS, Akgul Y, Kilic A (2016) A review on non-electro nanofibre spinning techniques. 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Is dependant on base polymer and processing conditions and applications only be as., melt and mold temperature ranges provided should only be used Bayreuth on social media Contact, Disclaimer. Impact of polymer Technology shear is an on-demand … polymer, fillers mold. Involves not only the shaping but also the synthesis, transformation, compounding,,. Nonelectrolytes3D edn conditions on the performance of P3HT: PCBM solar cells social media Contact Impressum! General guide stabilization of materials high moisture content in the polymer can … for LLDPE under these conditions reduce fracture! The impact of polymer Technology a significant impact on the performance of P3HT PCBM... With extended exposure to temperature the Figs ) for a minimum of 2 hours 195 F ) for a of.